Just to try to limit confusion about substrate, because I mentioned it.. I mentioned 'shinier', not related to durability. The flatter the mirror, the better. Roughness will help bonding (same reason people rough up a surface before gluing it), but not help good reflection, so there's a conflict of interests because a good polish reduces the available atomic bonds by reducing surface area to a minimum. So good adhesion depends on the chemical bonds available. This does not imply a direct relation with substrate durability, and I didn't think, or say, that it did.
For example, acrylic would make for lousy durability but bonding might be excellent because carbon in compounds usually leaves lots of free atomic bonds.
If anything, the relation is inverted as far as I know. If a mirror were made of diamond it would be very durable, but so few bonds available might make it hard to stick a coating on it. I don't know what this might mean for silicon mirrors but I guess those might be hard to make coatings stick to as well.

