It's safe all right. It's how the DT-40 pro's are supposed to be connected to a single-ended DAC. If you received the users manual for your scanners (actually it's not a manual at all, but rather a single sheet of paper) you'll see a diagram that looks like the one I posted above.
In any case, you aren't going to damage your galvos or your amps even if you conect the input signals incorrectly. (Well, let me qualify that - so long as you aren't overdriving them, you won't damage them.) You might get screwed-up images, but you won't break them.
Have a look at this page on the Pangolin site; it gives you several different ways to calculate scan angle.Is 2(1/tan(opposite/adjacent)) the right formula to find the angle?
It's a setting in your software. You don't need to measure it, you just select a speed and you're done.I have no idea how to measure the Kpps .
Adam